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The main tool for any serious gold maker is TradeSkillMaster. It is an addon suite with a desktop application that downloads price data and allows you to create rules for easy crafting, mailing, shopping and posting your items on the auction house. It has a premium service that includes e-mail notifications for great deals and importing great deals as a shopping scan.
TSM has a very steep learning curve, as it is a total profession framework. ITtdoes not hold your hand, and requires a lot of setup. Luckily you can import settings from other players and there are a ton of settings out there. I have published most of my settings in my pastebin here. You can also check out Sheyrahs. If you want to learn it from the ground up I suggest one of the following guides: PhatLewts, Sheyrah, WTBGold.
Once your auctioning operation reaches a certain size a second account becomes an invaluable tool. It will allow you to run auctioning scans, shopping scans and collect mailboxes while playing your main. I strongly suggest buying a second monitor as well. This will help you really unlock the benefit of a second account.